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ramé-hart Goniometer Accessories


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Automated Dispensing System
P/N 100-22-100

The ramé-hart Automated Dispensing System is a software-driven for producing precise pendant and sessile drops and is particularly useful for dynamic studies - such as advancing / receding studies. For more information, click here.



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Automated Tilting Base
P/N 100-25-A

Advancing and receding contact angles are readily determined by inclining the substrate and allowing the drop to deform as a function of gravity. By mounting a ramé-hart goniometer on the optional Automated Tilting Base, it is possible to incline not only the substrate but the entire instrument, preserving the optics-to-specimen alignment. This technique greatly expedites such measurements. The Automated Tilting Base is fully software driven and is supported by DROPimage Advanced v2.3 and above. This option is supported by Models 250 and 500.



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Manual Tilting Base
P/N 100-25-M

This tilting base is the same as 100-25-A except instead of being software-driven, it's manually driven -- with a hand crank. The 100-25-M can be upgraded to the Automated version with the upgrade kit p/n 100-25-U. This option is supported on every current-generation ramé-hart instrument.



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Environmental Chamber
P/N 100-07

This option, in conjunction with any Model 100-00, 300, or 500 ramé-hart goniometer, permits controlled conditions for the study of contact angle, surface energy, and surface tension. Controlled elevated temperatures to 300 C are produced by the integral electrical heaters, while sub-ambient temperatures can be produced by circulating a suitable coolant through the base of the chamber. Fittings for this purpose, and others for atmosphere control, are furnished. The chamber is suitable for vacuum use and pressures to 0.6 Atmospheres. Custom designed environmental chambers are available by special request. This option requires a Proportional Temperature Controller in if regulated elevated temperature is desired.

Additionally, a quartz cell (p/n 100-07-50) is available for liquid/liquid, inverted sessile drop, and captive bubble studies. A Cover with Stage assembly (p/n 100-09-10, shown below) is also available to facilitate advanced studies requiring a submerged adjustable stage.



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Proportional Temperature Controller
P/N 100-50

The ramé-hart Proportional Temperature Controller permits precisely regulated temperatures between ambient and 300° C and is used in conjunction with the ramé-hart Environmental Chamber p/n 100-07, Elevated Temperature Syringe p/n 100-11, and the ramé-hart High Pressure Chamber p/n 100-08. Available in 115V and 230V versions with



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Chamber Cover with Stage
P/N 100-09-10

Replaces the standard cover supplied with Chamber 100-07. Contains an externally adjustable substrate stage and permits studies of sessile drops on either side of substrate (normal and inverted), or captive bubbles on the underside. Substrate clamping will also accommodate films. Cover is equipped with an O-ring seal to interface with Elevated Temperature Syringe 100-11.



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Elevated Temperature Syringe
P/N 100-11

Functionally similar to the Micro-syringe Attachment 100-10, this unit permits forming drops of materials which have melting points as high as 230° C. May be used with Chamber 100-07 and Cover 100-09-10 for controlled environment studies. Test materials contact only glass and stainless steel.



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Film Clamps
P/N 100-15

The Film Clamps are furnished as a pair and mount directly to the working surface of the stage assembly of any ramé-hart goniometer. Their function is to maintain flatness of film-type substrates and they can also be utilized to secure specimens to the stage when using the tilting base to evaluate advancing and receding contact angles.



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Immersible Film Stage
P/N 100-16 

This unit fits within the interior of our Environmental Chamber, providing a convenient means of supporting small, film-type substrates. A screw-activated tensioning method is provided to eliminate ripples from the substrate.



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High Pressure Chamber
P/N 100-08

Use of this accessory with the ramé-hart goniometer permits liquid/liquid or liquid/liquid/solid studies to be performed at pressures of up to 68 Atmospheres and at temperatures to 230 C. Elevated temperatures are produced by integral electrical heaters. Liquid pressure is generated by a static pressurization system attached to the chamber. The chamber contains an externally adjustable substrate positioning stage. This high pressure chamber is for use with non-hazardous liquids only.



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Environmental Fixture
P/N 100-07-60

This unit provides evaporation or humidity control only. It incorporates our Model 100-07-50 Quartz Cell to provide distortion-free viewing. Outfitted with a suspension stage for solid substrate fixturing and/or immersion in bulk liquid of quartz vessel. This option is ideal for liquid/liquid studies, as well as captive bubble, and inverted sessile drop experiments.



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Quartz Cell
P/N 100-07-50

This Quartz Cell option is included with the Environmental Fixture p/n 100-07-60 and can be ordered as a replacement part for that option. The quartz cell also is designed to work inside of the Environmental Chamber p/n 100-07. It can also be used stand-alone for liquid/liquid and captive bubble studies.
Click here for more detailed specifications.



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Environmental Chamber with Humidity
P/N 100-07-H

This accessory permits studies under controlled conditions of humidity and temperature. Specifically designed for the semiconductor industry, the chamber contains a 4" rotating wafer support enabling multiple readings via an external control. Elevated temperatures to 230ş C and humidity levels up to 100% are generated and controlled by integral systems. A custom cover is designed per customer specifications according to the number and location of syringes desired.



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Rotating Wafer Support
P/N 100-21-xx

The rotating support maintains flatness and position of 4", 6", 8", 10" and 12" wafers in order to achieve contamination-free contact angle readings. It incorporates a rotating stage plate with displacement holes creating the appropriate suction. The wafer support mounts directly to the stage of the Contact Angle Goniometer. Requirements for larger wafer supports can be accommodated. Models 100-00, 300, and 500 support all sizes of rotating wafer. Model 400 supports and includes an 8" wafer support. Other models support smaller supports (4") only. Check current product matrix for detailed specifications.



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Vacuum Chuck Support
P/N 100-21-VCx

The 6" and 8" vacuum chuck support hold down large films and other flexible substrates while surface studies are performed. Supported on Models 100-00, 300, 400 and 500.



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Lead Frame Support
P/N 100-23 

This accessory maintains flatness and position of lead frames in order to achieve accurate contact angle for precise positioning of each testing surface. This support mounts directly to the stage of the Contact Angle Goniometer. Size requirements for various lead frames are easily accommodated by our manufacturing facility.



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Imaging Upgrade Kits
P/N 400-22-xx

For over 40 years, ramé-hart has built contact angle tools. Many of the legacy instruments, in particular Model 100-00 with a manual microscope, are still in use. Our manual-to-automated Imaging Kit provides all of the necessary components to upgrade a legacy instrument to function as a current-generation instrument. We add a digital FireWire camera, our DROPimage software, PC and LCD, and all necessary components to convert a legacy tool into a current generation tool allowing you to preserve your investment while keeping up with the advances in imaging technology. We have another upgrade kit that will upgrade any legacy analog camera system to a current-generation digital system which operates at 10 to 4 times faster than legacy camera systems.



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Microsyringe Fixture
P/N 100-10

 

The microsyringe fixture facilitates rapid and precise formation of pendant and sessile drops. Following placement of a sessile drop, the syringe is easily swung from the field of view. It will return to its exact working location for placement of the subsequent drop. Alternatively, it can remain at the working location, allowing the user to continuously add or withdraw fluid from a sessile drop for the purpose of forming advancing or receding contact angles. Test fluids contact only glass or Teflon within the micrometer-activated syringe. The interchangeable dispensing needles are stainless steel which readily form pendant or sessile drops.
This attachment is now included with all ramé-hart goniometer systems but is available as an option for users of our legacy instruments that did not include this accessory.



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Overhead Lighting Shade
P/N 100-24 

This accessory attaches to the micro-syringe fixture and provides effective blocking of overhead and ambient light sources, which if left unblocked, can frustrate the image quality and instrument accuracy of camera-based systems. Recommended for all automated goniometers in environments where ambient and overheard lighting causes reflection on the bubble. Models 200, 250, 300, and 500 that shipped after Jan 1 2004 include this fixture as standard equipment.


 

For more information, please email
carl@ramehart.com

©2008, ramé-hart instrument co. All rights reserved.

 

goniometer ramehart goniometer rame-hart goniometer ramé-hart goniometer contact angle NRL Zisman NRL Contact Angle Goniometer pendant drop sessile drop ramé-hart instrument co. rame-hart, inc. optical instrument fib

The ramé-hart contact angle goniometer was made in Mountain Lakes, NJ but is now made in Netcong, NJ. ramé-hart is also known as rame-hart ramehart and Rame-hart but ramé-hart is the correct spelling. The ramé-hart NRL goniometer was invented by Dr. William A. Zisman at the Navel Research Laboratory in Washington DC. The ramé-hart contact angle goniometer is used to measure contact angle, surface energy and surface tension. Carl Clegg is a salesman at ramé-hart instrument company. Ron Polo, Carmel Mulroy, and Gerd Fischer work at ramé-hart instrument company. The ramé-hart contact angle goniometer uses the pendant drop, sessile drop, and other methods. ramé-hart instrument co., formerly a part of rame-hart, inc. manufactures optical instruments. The fiber optic illuminator and Automated Dispensing System  are part of the system. The environmental chamber and proportional temperature controller are optional components as well as the environmental fixture, environmental chamber with humidity, high pressure chamber, circular vacuum chuck, humidity control, rotating wafer,  lead frame support. Finn Knut Hansen is the author of DROPimage Advanced and DROPimage Standard and DROPimage CA. The ramé-hart contact angle goniometer is availabe in the following models: Model 100 Model A100 Model A-100 Model 100-00 Model Model 100-F0 Model 120-F0 Model 200 Model 200-F1 Model 300 Model 300-F1 Model 250 Model 250-F1 Model 400-F1 Model 500 Model 500-F1; the 3-axis stage rail is avialable in 16" 20" 21". Dr. Zisman of the Naval Research Lab NRL in Washington DC stuided adhesion, wettability, contact angle and surface science  including monolayers energetics, static dynamic contact angle, velocity, viscosity, interfacial (behaviour) behavior, contact angle interpretation and hysteresis energetics, surface contamination, cleaning polymer coatings, characterization and application of polymided synthesis particles on surfaces,  metallized plastics, silanes and other coupling agents, polymer surface modification, relevance to adhesion acid base acid-base, dynamic surface characterization, mittal tissue, films, coatings, coupling agents, powders fibers, wood products, papers, polymers, monolayers, bioadhesion, ophthalmology, surface science, instruments,  liquid, solid surface energy, surface tension interface, interfacial tension analysis,  quantitative measure of the wetting of a solid by a liquid. Analysis characterizes the wettability of a surface by measuring the contact angle. Contact angle describes the shape of a liquid droplet resting on a solid surface. The roughness of a surface improves the wettability for hydrophilic surfaces; hydrophobic surfaces. Young's equation, which interrelates the contact angle and surface tensions of the liquid and solid phases. International Symposium on Contact Angle, Wettability and Adhesion. The angle of contact is the angle between the tangent to the periphery of the point of contact with the solid. Capillarity is an effect when liquid in a narrow vertical tube becomes elevated or depressed. When a liquid does not spread on a substrate (usually a solid), a contact. angle (θ) is formed which is defined as the angle. Contact angle measuring unit for characterization of hydrophobicity of film surfaces are used in controlling cleaning processes. A computer controlled contact angle analyzer makes it easy to measure static and dynamic contact angle, along with surface tension and surface energy. CONTACT ANGLE MEASUREMENT is a common method to obtain surface energies of materials. The measurement by itself is nothing novel; however, the relationship of contact angle to surface energetics requires a good deal of understanding. I have published several papers regarding various aspects of that relationship, especially related to polymers. Surface energy quantifies the disruption of chemical bonds that occurs when a surface is created. In the physics of solids, surfaces. The contact angle is the angle at which a liquid/vapor interface meets the solid surface. The contact angle is specific for any given system and is determined by the interactions across the three interfaces. Most often the concept is illustrated with a small liquid droplet resting on a flat horizontal solid surface. The shape of the droplet is determined by the Young-Laplace equation. The contact angle plays the role of a boundary condition. Contact angle is measured using a contact angle goniometer. The contact angle is not limited to a liquid/vapor interface; it is equally applicable to the interface of two liquids or two vapors. The static sessile drop method The sessile drop method is measured by a contact angle goniometer using an optical subsystem to capture the profile of a pure liquid on a solid substrate. The angle formed between the liquid/solid interface and the liquid/vapor interface is the contact angle. Older systems used a microscope optical system with a back light. Current-generation systems employ high resolutions cameras and software to capture and analyze the contact angle. The dynamic sessile drop method The dynamic sessile drop is similar to the static sessile drop but requires the drop to be modified. A common type of dynamic sessile drop study determines the largest contact angle possible without increasing its solid/liquid interfacial area by adding volume dynamically. This maximum angle is the advancing angle. Volume is removed to produce the smallest possible angle, the receding angle. The difference between the advancing and receding angle is the contact angle hysteresis. Dynamic Wilhelmy method A method for calculating average advancing and receding contact angles on solids of uniform geometry. Both sides of the solid must have the same properties. Wetting force on the solid is measured as the solid is immersed in or withdrawn from a liquid of known surface tension. Single-fiber Wilhelmy method Dynamic Wilhelmy method applied to single fibers to measure advancing and receding contact angles. Powder contact angle method Enables measurement of average contact angle and sorption speed for powders and other porous materials. Change of weight as a function of time is measured. The dynamic contact angles of water on these surfaces are carefully measured and found to be consistent with the theoretical predictions of the Cassie model and the Wenzel model. When a water drop is at the Wenzel state, its contact angle hysteresis increases along with an increase in the surface roughness. While the surface roughness is further raised beyond its transition roughness (from the Wenzel state to the Cassie state), the contact angle hysteresis (or receding contact angle) discontinuously drops (or jumps) to a lower (or higher) value. In surface science, an instrument generally called a contact angle goniometer is used to measure the contact angle at which a liquid/vapor interface meets a solid surface. The first contact angle goniometer was designed by Dr. William Zisman of the United States Naval Research Laboratory in Washington, DC and manufactured by ramé-hart of Mountain Lakes, NJ. This tool is used not only for contact angle and surface energy applications, but also to measure surface tension using pendant drop, sessile drop, and other methods. The original manual contact angle goniometer used an eyepiece with microscope. The current generation of contact angle instruments uses cameras and software to capture and analyze the drop shape and are better suited for dynamic and advanced studies. Surface energy is most commonly quantified using a contact angle goniometer and a number of different methods. Thomas Young described surface energy as the interaction between the forces of cohesion and the forces of adhesion which, in turn, dictate if wetting occurs. If wetting occurs, the drop will spread out flat. In most cases, however, the drop will bead to some extent and by measuring the contact angle formed where the drop makes contact with the solid the surface energies of the system can be measured. Young also developed the well-regarded Young's Modulus which is used to measure the stiffness of a material as well as Young's Equation which defines the balances of forces caused by a wet drop on a dry surface. If the surface is hydrophobic then the contact angle of a drop of water will be larger. Hydrophilicity is indicated by smaller contact angles and higher surface energy. Water has high surface energy by nature; it's polar and forms hydrogen bonds. In the case of "dry wetting", one can use the Young-Dupree equation which is expressed by the work of adhesion. This method accounts for the surface pressure of the liquid vapor which can be significant. Pierre-Gilles De Gennes, a Nobel Prize Laureate in Physics, describes wet and dry wetting and how the difference between the two relates to whether or not the vapor is saturated .